全文获取类型
收费全文 | 6304篇 |
免费 | 871篇 |
国内免费 | 414篇 |
专业分类
化学 | 988篇 |
晶体学 | 59篇 |
力学 | 1006篇 |
综合类 | 114篇 |
数学 | 3431篇 |
物理学 | 1991篇 |
出版年
2024年 | 6篇 |
2023年 | 53篇 |
2022年 | 69篇 |
2021年 | 136篇 |
2020年 | 165篇 |
2019年 | 136篇 |
2018年 | 183篇 |
2017年 | 182篇 |
2016年 | 247篇 |
2015年 | 155篇 |
2014年 | 298篇 |
2013年 | 461篇 |
2012年 | 323篇 |
2011年 | 368篇 |
2010年 | 330篇 |
2009年 | 382篇 |
2008年 | 355篇 |
2007年 | 398篇 |
2006年 | 341篇 |
2005年 | 341篇 |
2004年 | 294篇 |
2003年 | 273篇 |
2002年 | 263篇 |
2001年 | 205篇 |
2000年 | 214篇 |
1999年 | 172篇 |
1998年 | 136篇 |
1997年 | 120篇 |
1996年 | 120篇 |
1995年 | 90篇 |
1994年 | 93篇 |
1993年 | 95篇 |
1992年 | 74篇 |
1991年 | 72篇 |
1990年 | 58篇 |
1989年 | 37篇 |
1988年 | 43篇 |
1987年 | 32篇 |
1986年 | 34篇 |
1985年 | 36篇 |
1984年 | 38篇 |
1983年 | 13篇 |
1982年 | 34篇 |
1981年 | 29篇 |
1980年 | 13篇 |
1979年 | 13篇 |
1978年 | 9篇 |
1977年 | 14篇 |
1976年 | 11篇 |
1973年 | 8篇 |
排序方式: 共有7589条查询结果,搜索用时 15 毫秒
1.
通过引入参数,构造了一个全平面上的、含双曲函数的非齐次核函数。利用正切函数的有理分式展开,建立了最佳常数因子与正切函数高阶导数相关联的Hilbert型积分不等式。 作为应用,通过赋予参数不同的值,建立了一些有意义的特殊结果。 相似文献
2.
《中国物理 B》2021,30(5):56501-056501
Thermal expansion control is always an obstructive factor and challenging in high precision engineering field. Here,the negative thermal expansion of Nb F_3 and Nb OF_2 was predicted by first-principles calculation with density functional theory and the quasi-harmonic approximation(QHA). We studied the total charge density, thermal vibration, and lattice dynamic to investigate the thermal expansion mechanism. We found that the presence of O induced the relatively strong covalent bond in Nb OF_2, thus weakening the transverse vibration of F and O in Nb OF_2, compared with the case of Nb F_3.In this study, we proposed a way to tailor negative thermal expansion of metal fluorides by introducing the oxygen atoms.The present work not only predicts two NTE compounds, but also provides an insight on thermal expansion control by designing chemical bond type. 相似文献
3.
利用标量化方法建立对称向量拟均衡问题有效解的存在性定理。作为标量化方法的应用,利用这一方法得到向量变分不等式和拟向量变分不等式有效解的存在性定理。 相似文献
4.
Phan Quoc Khanh 《Numerical Functional Analysis & Optimization》2018,39(1):100-125
We propose a definition of a generalized type of Knaster–Kuratowski–Mazurkiewicz (KKM) mappings, called a weak T-KKM mapping, and a corresponding weak KKM property. A new extension of the Fan–Glicksberg fixed-point theorem is established. Sufficient conditions for the existence of a continuous selection, a fixed point of a composition, and a coincidence point are also provided. Then, we use the obtained results to study the existence of solutions to various optimization-related problems. Discussions and detailed examples are included as well to compare our results with existing ones and to explain their advantages in many situations. 相似文献
5.
AbstractWe study the inverse problem of parameter identification in noncoercive variational problems that commonly appear in applied models. We examine the differentiability of the set-valued parameter-to-solution map using the first-order and the second-order contingent derivatives. We explore the inverse problem using the output least-squares and the modified output least-squares objectives. By regularizing the noncoercive variational problem, we obtain a single-valued regularized parameter-to-solution map and investigate its smoothness and boundedness. We also consider optimization problems using the output least-squares and the modified output least-squares objectives for the regularized variational problem. We give a complete convergence analysis showing that for the output least-squares and the modified output least-squares, the regularized minimization problems approximate the original optimization problems suitably. We also provide the first-order and the second-order adjoint method for the computation of the first-order and the second-order derivatives of the output least-squares objective. We provide discrete formulas for the gradient and the Hessian calculation and present numerical results. 相似文献
6.
In this paper, we investigate the evolution of joint invariants under invariant geometric flows using the theory of equivariant moving frames and the induced invariant discrete variational complex. For certain arc length preserving planar curve flows invariant under the special Euclidean group , the special linear group , and the semidirect group , we find that the induced evolution of the discrete curvature satisfies the differential‐difference mKdV, KdV, and Burgers' equations, respectively. These three equations are completely integrable, and we show that a recursion operator can be constructed by precomposing the characteristic operator of the curvature by a certain invariant difference operator. Finally, we derive the constraint for the integrability of the discrete curvature evolution to lift to the evolution of the discrete curve itself. 相似文献
7.
采用量子统计系综理论,研究了基态NO分子宏观气体摩尔熵、摩尔内能、摩尔热容等热力学性质.首先应用课题组前期建立的变分代数法(variational algebraic method, VAM)计算获得了基态NO分子的完全振动能级,得到的VAM振动能级作为振动部分,结合欧拉-麦克劳林渐进展开公式的转动贡献,应用于经典的热力学与统计物理公式中,从而计算得到了1000-5000 K温度范围内NO宏观气体的摩尔内能、摩尔熵和摩尔热容.将不同方法计算得到的摩尔热容结果分别与实验值进行比较,结果表明基于VAM完全振动能级获得的结果优于其他方法获得的理论结果.振动部分采用谐振子模型对无限能级求和计算热力学性质的方法有一定的局限性,应当使用有限的完全振动能级进行统计求和. 相似文献
8.
In the recent decade, the meshless methods have been handled for solving most of PDEs due to easiness of the meshless methods. One of the popular meshless methods is the element-free Galerkin (EFG) method that was first proposed for solving some problems in the solid mechanics. The test and trial functions of the EFG are based on the special basis. Recently, some modifications have been developed to improve the EFG method. One of these improvements is the variational multiscale EFG procedure. In the current article, the shape functions of interpolation moving least squares approximation have been applied to the variational multiscale EFG technique for solving the incompressible magnetohydrodynamics flow. In order to reduce the elapsed CPU time of simulation, we employ a reduced-order model based on the proper orthogonal decomposition technique. The current combination can be referred to as the reduced-order variational multiscale EFG technique. To illustrate the reduction in CPU time used as well as the efficiency of the proposed method, we applied it for the two-dimensional cases. 相似文献
9.
Above,below, and in‐between the two glass transitions of ultrathin free‐standing polystyrene films: Thermal expansion coefficient and physical aging 下载免费PDF全文
In previous work we observed two simultaneous transitions in high molecular weight (MW) free‐standing polystyrene films that were interpreted as two thickness‐dependent reduced glass transition temperatures (Tgs). The weaker lower transition agreed well with the MW‐dependent Tg(h) previously reported, while the much stronger upper transition matched the MW‐independent Tg(h) previously observed in low‐MW free‐standing films. Here, we investigate the nature of these two transitions by inspecting the temperature dependence of the films' thermal coefficient of expansion (TCE) and present physical aging measurements using ellipsometry both below and in‐between the two transitions. TCE values indicate approximately 80 to 90% of the film solidifies at the upper transition, while only 10 to 20% remains mobile to lower temperatures, freezing out at the lower transition. Physical aging is observed at a temperature below the upper transition, but above the lower transition, indicative of the upper transition being an actual glass transition associated with the α‐relaxation. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 64–75 相似文献
10.
Modes obtained using the Proper Orthogonal Decomposition are used as boundary enrichment functions within a variational multiscale method for the stochastically forced Burgers equation. Initially, large increases in accuracy are obtained using the enrichment functions without stabilisation terms. Then, optimal coefficients for the stabilisation parameter τ of the unresolved scale model are calibrated using a goal‐oriented model‐constrained optimisation technique, resulting in further improvements. As both the determination of the enrichment functions and the optimisation of the coefficients requires high‐accuracy reference data, a scaling procedure is introduced to allow their use over range of conditions. Numerical experiments confirm that the scaling procedure is effective. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献